Polypyrrole films functionalized with pendant titanocene dichloride complexes : Ellipsometric study of the electropolymerization process
Identifieur interne : 007279 ( Main/Repository ); précédent : 007278; suivant : 007280Polypyrrole films functionalized with pendant titanocene dichloride complexes : Ellipsometric study of the electropolymerization process
Auteurs : RBID : Pascal:08-0152522Descripteurs français
- Pascal (Inist)
- Pyrrole polymère, Fonctionnalisation, Ellipsométrie, Polymérisation électrolytique, Acétonitrile, Spectrométrie absorption, Titane Complexe, Titane Composé organique, Complexe chloro, Electrode, Platine, Solvant organique, Propriété optique, Indice réfraction, Indice extinction, Potentiel électrode, Electrode ITO, Spectrométrie UV visible, Polymère conducteur, Métallocène, Réaction électrochimique, Titanocène complexe.
- Wicri :
- concept : Platine.
English descriptors
- KwdEn :
- Absorption spectrometry, Acetonitrile, Chloro complex, Conducting polymers, Electrochemical polymerization, Electrochemical reaction, Electrode potential, Electrodes, Ellipsometry, Extinction index, Functionalization, Indium tin oxide electrode, Metallocene, Optical properties, Organic solvent, Platinum, Pyrrole polymer, Refraction index, Titanium Complexes, Titanium Organic compounds, Ultraviolet visible spectrometry.
Abstract
Electrochemical and ellipsometric methods have been used to study the electropolymerization process of a functionalized monomer, Tc3Py (in which pyrrole is covalently bonded with titanocene dichloride complex) on platinum electrode from a dilute monomer solution in acetonitrile. The deposition has been performed in the potentiodynamic regime. A new method for the acquisition and treatment of ellipsometric data has been proposed which allowed us to analyze the evolution of the film properties at each potential. The model of a single uniform layer was unable to describe the ellipsometric experimental observations with the necessary precision. A proper fitting of the data has been achieved considering a model of two layers having identical values of the refractive index but different values of the extinction coefficient (higher absorption for the outer layer). The analysis of the calculated values of the optical parameters of these layers has led to the assumption that both layers represent morphologically the same medium (i.e. that the whole polymer film is uniform) while the higher extinction coefficient of the external layer was due to a penetration into it of solute oligomers possessing an intensive absorption at the wavelength of the observation, 633 nm. The dependences of the thicknesses of each layer and of the whole film on the cycle number have been established, the increment of the growth (5.5 nm per cycle) being constant within the whole deposition procedure. The variation of the optical constants of the layers during the potential cycling was determined and interpreted. The calculated values for the extinction coefficients and the layer thicknesses have been used to estimate how the film absorbance changes during the potential cycling. Its comparison with the same characteristic measured directly in a spectroelectrochemical cell for a film deposited at the ITO electrode surface has provided an extra evidence in favor of the above hypothesis on the film being a morphologically uniform material, with incorporated solute oligomers in its outer layer.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Polypyrrole films functionalized with pendant titanocene dichloride complexes : Ellipsometric study of the electropolymerization process</title><author><name sortKey="Correi, J P" uniqKey="Correi J">J. P. Correi</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>CQB, Faculdade de Ciências da Universidade de Lisboa</s1><s2>Lisboa</s2><s3>PRT</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Portugal</country><wicri:noRegion>Lisboa</wicri:noRegion></affiliation></author><author><name sortKey="Graczyk, M" uniqKey="Graczyk M">M. Graczyk</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LSEO-UMR 5188 CNRS, Université de Bourgogne</s1><s2>Dijon</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>France</country><placeName><region type="région">Bourgogne</region><settlement type="city">Dijon</settlement></placeName><orgName type="university">Université de Bourgogne</orgName><placeName><settlement type="city">Dijon</settlement><region type="region" nuts="2">Région Bourgogne</region></placeName></affiliation></author><author><name sortKey="Abrantes, L M" uniqKey="Abrantes L">L. M. Abrantes</name><affiliation wicri:level="1"><inist:fA14 i1="01"><s1>CQB, Faculdade de Ciências da Universidade de Lisboa</s1><s2>Lisboa</s2><s3>PRT</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></inist:fA14><country>Portugal</country><wicri:noRegion>Lisboa</wicri:noRegion></affiliation></author><author><name sortKey="Vorotyntsev, M A" uniqKey="Vorotyntsev M">M. A. Vorotyntsev</name><affiliation wicri:level="4"><inist:fA14 i1="02"><s1>LSEO-UMR 5188 CNRS, Université de Bourgogne</s1><s2>Dijon</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>France</country><placeName><region type="région">Bourgogne</region><settlement type="city">Dijon</settlement></placeName><orgName type="university">Université de Bourgogne</orgName><placeName><settlement type="city">Dijon</settlement><region type="region" nuts="2">Région Bourgogne</region></placeName></affiliation></author></titleStmt><publicationStmt><idno type="inist">08-0152522</idno><date when="2007">2007</date><idno type="stanalyst">PASCAL 08-0152522 INIST</idno><idno type="RBID">Pascal:08-0152522</idno><idno type="wicri:Area/Main/Corpus">006D38</idno><idno type="wicri:Area/Main/Repository">007279</idno></publicationStmt><seriesStmt><idno type="ISSN">0013-4686</idno><title level="j" type="abbreviated">Electrochim. acta</title><title level="j" type="main">Electrochimica acta</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Absorption spectrometry</term><term>Acetonitrile</term><term>Chloro complex</term><term>Conducting polymers</term><term>Electrochemical polymerization</term><term>Electrochemical reaction</term><term>Electrode potential</term><term>Electrodes</term><term>Ellipsometry</term><term>Extinction index</term><term>Functionalization</term><term>Indium tin oxide electrode</term><term>Metallocene</term><term>Optical properties</term><term>Organic solvent</term><term>Platinum</term><term>Pyrrole polymer</term><term>Refraction index</term><term>Titanium Complexes</term><term>Titanium Organic compounds</term><term>Ultraviolet visible spectrometry</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Pyrrole polymère</term><term>Fonctionnalisation</term><term>Ellipsométrie</term><term>Polymérisation électrolytique</term><term>Acétonitrile</term><term>Spectrométrie absorption</term><term>Titane Complexe</term><term>Titane Composé organique</term><term>Complexe chloro</term><term>Electrode</term><term>Platine</term><term>Solvant organique</term><term>Propriété optique</term><term>Indice réfraction</term><term>Indice extinction</term><term>Potentiel électrode</term><term>Electrode ITO</term><term>Spectrométrie UV visible</term><term>Polymère conducteur</term><term>Métallocène</term><term>Réaction électrochimique</term><term>Titanocène complexe</term></keywords><keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Platine</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Electrochemical and ellipsometric methods have been used to study the electropolymerization process of a functionalized monomer, Tc3Py (in which pyrrole is covalently bonded with titanocene dichloride complex) on platinum electrode from a dilute monomer solution in acetonitrile. The deposition has been performed in the potentiodynamic regime. A new method for the acquisition and treatment of ellipsometric data has been proposed which allowed us to analyze the evolution of the film properties at each potential. The model of a single uniform layer was unable to describe the ellipsometric experimental observations with the necessary precision. A proper fitting of the data has been achieved considering a model of two layers having identical values of the refractive index but different values of the extinction coefficient (higher absorption for the outer layer). The analysis of the calculated values of the optical parameters of these layers has led to the assumption that both layers represent morphologically the same medium (i.e. that the whole polymer film is uniform) while the higher extinction coefficient of the external layer was due to a penetration into it of solute oligomers possessing an intensive absorption at the wavelength of the observation, 633 nm. The dependences of the thicknesses of each layer and of the whole film on the cycle number have been established, the increment of the growth (5.5 nm per cycle) being constant within the whole deposition procedure. The variation of the optical constants of the layers during the potential cycling was determined and interpreted. The calculated values for the extinction coefficients and the layer thicknesses have been used to estimate how the film absorbance changes during the potential cycling. Its comparison with the same characteristic measured directly in a spectroelectrochemical cell for a film deposited at the ITO electrode surface has provided an extra evidence in favor of the above hypothesis on the film being a morphologically uniform material, with incorporated solute oligomers in its outer layer.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0013-4686</s0></fA01><fA02 i1="01"><s0>ELCAAV</s0></fA02><fA03 i2="1"><s0>Electrochim. acta</s0></fA03><fA05><s2>53</s2></fA05><fA06><s2>3</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Polypyrrole films functionalized with pendant titanocene dichloride complexes : Ellipsometric study of the electropolymerization process</s1></fA08><fA09 i1="01" i2="1" l="ENG"><s1>Innovative electrochemistry enterprising science: selection of papers from the 57th annual meeting of the International Society of Electrochemistry, 27 August-1 September 2006, Edinburgh, UK</s1></fA09><fA11 i1="01" i2="1"><s1>CORREI (J. P.)</s1></fA11><fA11 i1="02" i2="1"><s1>GRACZYK (M.)</s1></fA11><fA11 i1="03" i2="1"><s1>ABRANTES (L. M.)</s1></fA11><fA11 i1="04" i2="1"><s1>VOROTYNTSEV (M. A.)</s1></fA11><fA12 i1="01" i2="1"><s1>NOVAK (P.)</s1><s9>ed.</s9></fA12><fA12 i1="02" i2="1"><s1>GORTON (L.)</s1><s9>ed.</s9></fA12><fA12 i1="03" i2="1"><s1>MOFFAT (T. P.)</s1><s9>ed.</s9></fA12><fA12 i1="04" i2="1"><s1>BILEWICZ (R.)</s1><s9>ed.</s9></fA12><fA12 i1="05" i2="1"><s1>HEINZE (J.)</s1><s9>ed.</s9></fA12><fA12 i1="06" i2="1"><s1>KOPPER (M. T. M.)</s1><s9>ed.</s9></fA12><fA12 i1="07" i2="1"><s1>MARCUS (P.)</s1><s9>ed.</s9></fA12><fA12 i1="08" i2="1"><s1>TRASATTI (S.)</s1><s9>ed.</s9></fA12><fA14 i1="01"><s1>CQB, Faculdade de Ciências da Universidade de Lisboa</s1><s2>Lisboa</s2><s3>PRT</s3><sZ>1 aut.</sZ><sZ>3 aut.</sZ></fA14><fA14 i1="02"><s1>LSEO-UMR 5188 CNRS, Université de Bourgogne</s1><s2>Dijon</s2><s3>FRA</s3><sZ>2 aut.</sZ><sZ>4 aut.</sZ></fA14><fA15 i1="01"><s1>Paul Scherrer Institute</s1><s2>Villigen</s2><s3>CHE</s3><sZ>1 aut.</sZ></fA15><fA15 i1="02"><s1>Lund University</s1><s2>Lund</s2><s3>SWE</s3><sZ>2 aut.</sZ></fA15><fA15 i1="03"><s1>Nat. Inst. Stand. & Technol. (NIST)</s1><s2>Gaithersburg, MD</s2><s3>USA</s3><sZ>3 aut.</sZ></fA15><fA15 i1="04"><s1>Warsaw University</s1><s2>Warsaw</s2><s3>POL</s3><sZ>4 aut.</sZ></fA15><fA15 i1="05"><s1>Albert-Ludwigs Universität</s1><s2>Freiburg</s2><s3>DEU</s3><sZ>5 aut.</sZ></fA15><fA15 i1="06"><s1>Leiden University</s1><s2>Leiden</s2><s3>NLD</s3><sZ>6 aut.</sZ></fA15><fA15 i1="07"><s1>Université Pierre et Marie Curie</s1><s2>Paris</s2><s3>FRA</s3><sZ>7 aut.</sZ></fA15><fA15 i1="08"><s1>University of Milan</s1><s2>Milan</s2><s3>ITA</s3><sZ>8 aut.</sZ></fA15><fA18 i1="01" i2="1"><s1>International Society of Electrochemistry</s1><s2>Lausanne</s2><s3>CHE</s3><s9>org-cong.</s9></fA18><fA20><s1>1195-1205</s1></fA20><fA21><s1>2007</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>1516</s2><s5>354000174206480200</s5></fA43><fA44><s0>0000</s0><s1>© 2008 INIST-CNRS. All rights reserved.</s1></fA44><fA45><s0>69 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>08-0152522</s0></fA47><fA60><s1>P</s1><s2>C</s2></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Electrochimica acta</s0></fA64><fA66 i1="01"><s0>GBR</s0></fA66><fC01 i1="01" l="ENG"><s0>Electrochemical and ellipsometric methods have been used to study the electropolymerization process of a functionalized monomer, Tc3Py (in which pyrrole is covalently bonded with titanocene dichloride complex) on platinum electrode from a dilute monomer solution in acetonitrile. The deposition has been performed in the potentiodynamic regime. A new method for the acquisition and treatment of ellipsometric data has been proposed which allowed us to analyze the evolution of the film properties at each potential. The model of a single uniform layer was unable to describe the ellipsometric experimental observations with the necessary precision. A proper fitting of the data has been achieved considering a model of two layers having identical values of the refractive index but different values of the extinction coefficient (higher absorption for the outer layer). The analysis of the calculated values of the optical parameters of these layers has led to the assumption that both layers represent morphologically the same medium (i.e. that the whole polymer film is uniform) while the higher extinction coefficient of the external layer was due to a penetration into it of solute oligomers possessing an intensive absorption at the wavelength of the observation, 633 nm. The dependences of the thicknesses of each layer and of the whole film on the cycle number have been established, the increment of the growth (5.5 nm per cycle) being constant within the whole deposition procedure. The variation of the optical constants of the layers during the potential cycling was determined and interpreted. The calculated values for the extinction coefficients and the layer thicknesses have been used to estimate how the film absorbance changes during the potential cycling. Its comparison with the same characteristic measured directly in a spectroelectrochemical cell for a film deposited at the ITO electrode surface has provided an extra evidence in favor of the above hypothesis on the film being a morphologically uniform material, with incorporated solute oligomers in its outer layer.</s0></fC01><fC02 i1="01" i2="X"><s0>001C01H05</s0></fC02><fC02 i1="02" i2="X"><s0>001D09B01</s0></fC02><fC03 i1="01" i2="X" l="FRE"><s0>Pyrrole polymère</s0><s2>NK</s2><s5>01</s5></fC03><fC03 i1="01" i2="X" l="ENG"><s0>Pyrrole polymer</s0><s2>NK</s2><s5>01</s5></fC03><fC03 i1="01" i2="X" l="SPA"><s0>Pirrol polímero</s0><s2>NK</s2><s5>01</s5></fC03><fC03 i1="02" i2="X" l="FRE"><s0>Fonctionnalisation</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="ENG"><s0>Functionalization</s0><s5>02</s5></fC03><fC03 i1="02" i2="X" l="SPA"><s0>Funciónalización</s0><s5>02</s5></fC03><fC03 i1="03" i2="X" l="FRE"><s0>Ellipsométrie</s0><s5>03</s5></fC03><fC03 i1="03" i2="X" 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extinción</s0><s5>15</s5></fC03><fC03 i1="16" i2="X" l="FRE"><s0>Potentiel électrode</s0><s5>16</s5></fC03><fC03 i1="16" i2="X" l="ENG"><s0>Electrode potential</s0><s5>16</s5></fC03><fC03 i1="16" i2="X" l="SPA"><s0>Potencial electrodo</s0><s5>16</s5></fC03><fC03 i1="17" i2="X" l="FRE"><s0>Electrode ITO</s0><s5>17</s5></fC03><fC03 i1="17" i2="X" l="ENG"><s0>Indium tin oxide electrode</s0><s5>17</s5></fC03><fC03 i1="17" i2="X" l="SPA"><s0>Electrodo ITO</s0><s5>17</s5></fC03><fC03 i1="18" i2="X" l="FRE"><s0>Spectrométrie UV visible</s0><s5>18</s5></fC03><fC03 i1="18" i2="X" l="ENG"><s0>Ultraviolet visible spectrometry</s0><s5>18</s5></fC03><fC03 i1="18" i2="X" l="SPA"><s0>Espectrometría UV visible</s0><s5>18</s5></fC03><fC03 i1="19" i2="3" l="FRE"><s0>Polymère conducteur</s0><s5>32</s5></fC03><fC03 i1="19" i2="3" l="ENG"><s0>Conducting polymers</s0><s5>32</s5></fC03><fC03 i1="20" i2="X" l="FRE"><s0>Métallocène</s0><s5>33</s5></fC03><fC03 i1="20" i2="X" l="ENG"><s0>Metallocene</s0><s5>33</s5></fC03><fC03 i1="20" i2="X" l="SPA"><s0>Metaloceno</s0><s5>33</s5></fC03><fC03 i1="21" i2="X" l="FRE"><s0>Réaction électrochimique</s0><s5>36</s5></fC03><fC03 i1="21" i2="X" l="ENG"><s0>Electrochemical reaction</s0><s5>36</s5></fC03><fC03 i1="21" i2="X" l="SPA"><s0>Reacción electroquímica</s0><s5>36</s5></fC03><fC03 i1="22" i2="X" l="FRE"><s0>Titanocène complexe</s0><s2>NK</s2><s4>INC</s4><s5>76</s5></fC03><fC07 i1="01" i2="X" l="FRE"><s0>Métal transition Complexe</s0><s2>NC</s2><s2>NA</s2><s5>53</s5></fC07><fC07 i1="01" i2="X" l="ENG"><s0>Transition metal Complexes</s0><s2>NC</s2><s2>NA</s2><s5>53</s5></fC07><fC07 i1="01" i2="X" l="SPA"><s0>Metal transición Complejo</s0><s2>NC</s2><s2>NA</s2><s5>53</s5></fC07><fC07 i1="02" i2="X" l="FRE"><s0>Métal transition</s0><s2>NC</s2><s5>54</s5></fC07><fC07 i1="02" i2="X" l="ENG"><s0>Transition metal</s0><s2>NC</s2><s5>54</s5></fC07><fC07 i1="02" i2="X" l="SPA"><s0>Metal transición</s0><s2>NC</s2><s5>54</s5></fC07><fN21><s1>091</s1></fN21></pA><pR><fA30 i1="01" i2="1" l="ENG"><s1>International Society of Electrochemistry ISE. Annual meeting</s1><s2>57</s2><s3>Edinburgh GBR</s3><s4>2006-08-27</s4></fA30></pR></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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|type= RBID
|clé= Pascal:08-0152522
|texte= Polypyrrole films functionalized with pendant titanocene dichloride complexes : Ellipsometric study of the electropolymerization process
}}
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